Nanoscience

Hexagonal boron nitride, stacked layers of boron and nitrogen atoms arranged in a hexagonal lattice, has recently been found to bend electromagnetic energy in unusual and potentially useful ways.

Last year Fogler and colleagues demonstrated that light could be stored within nanoscale granules of hexagonal boron nitride. Now Fogler’s research group has published a new paper in the journal Nano Letters that elaborates how this trapped light behaves inside the granules.

The particles of light, called phonon polaritons, disobey standard laws of reflection as they bounce through the granules, but their movement isn’t random. Polariton rays propagate along paths at fixed angles with respect to the atomic structure of the material, Folger’s team reports. That can lead to interesting resonances.

“The trajectories of the trapped polariton rays are very convoluted in most instances,” Fogler said. “However, at certain ‘magic’ frequencies they can become simple closed orbits.”

When that happens “hot spots” of strongly enhanced electrical fields can emerge. Fogler’s group found those can form elaborate geometric patterns in granules of spheroidal shape.

The polaritons are not only particles but also waves that form interference patterns. When overlaid on the hot contours of enhanced electrical fields, these create strikingly beautiful images.

“They resemble Fabergé eggs, the gem-encrusted treasures of the Russian tsars,” Fogler observed.

Beyond creating beautiful images, their analysis illustrates the way light is stored inside the material. The patterns and the magic frequencies are determined not by the size of the spheroid but its shape, that is, the ratio of its girth to length. The analysis revealed that a single parameter determines the fixed angle along which polariton rays propagate with respect to the surface of the spheroids.

Scientists are beginning to find practical uses for materials such as hexagonal boron nitride that manipulate light in usual ways. The theory this work informed could guide the development of applications such as nanoresonators for high-resolution color filtering and spectral imaging, hyperlenses for subdiffractional imaging, or infrared photon sources.

The analysis provides a theoretical explanation for earlier observations of trapped light. Fogler and colleagues suggest several experiments that could confirm their prediction of orbiting light using advanced optical techniques, some of which are underway, Fogler said. “The experimental quest to detect orbiting polaritons has already begun.”

Story Source:

The above post is reprinted from materials provided by University of California – San Diego. The original item was written by Susan Brown. Note: Materials may be edited for content and length.

Journal Reference:

1. Zhiyuan Sun, Á. Gutiérrez-Rubio, D. N. Basov, M. M. Fogler. Hamiltonian Optics of Hyperbolic Polaritons in Nanogranules. Nano Letters, 2015; 15 (7): 4455 DOI: 10.1021/acs.nanolett.5b00814

University of California – San Diego. (2015, July 16). Trapped light orbits within an intriguing material. ScienceDaily. Retrieved October 12, 2015 from www.sciencedaily.com/releases/2015/07/150716141605.htm